@article{34820, author = {Piyachai Khomein and Asritha Nallapaneni and Jonathan Lau and Drew Lilley and Chenhui Zhu and Sumanjeet Kaur and Ravi S Prasher and Gao Liu}, title = {Random copolymer of poly(polyethylene glycol methyl ether)methacrylate as tunable transition temperature solid-solid phase change material for thermal energy storage}, abstract = {

Polymer based phase change materials (PCM) for thermal energy storage (TES) applications have gained some attention recently due to their high stability and potential solid to solid phase transition. Here, we are the first to utilize a simple copolymerization strategy for static tunability transition temperature (T_t) of polymeric PCM. The copolymerization between short and long side chain polyethylene glycol based methacrylate polymers was designed to tune T_t with minimum impact on their energy density. Polarized optical microscope and x-ray techniques were also used to understand the relationship between crystal structure and T_t of different copolymer composition which was discussed in the context. The solid to solid transition polymeric PCM were successfully developed with tunable T_t ranged from 18 °C to 35 °C which is suitable toward building envelop applications.

}, year = {2021}, journal = {Solar Energy Materials and Solar Cells}, volume = {225}, pages = {111030}, month = {03/2021}, issn = {09270248}, doi = {10.1016/j.solmat.2021.111030}, language = {eng}, }