@article{34203, author = {José R Chirinos and Dayana D Oropeza and Jhanis J Gonzalez and Vassilia Zorba and Richard E Russo}, title = {Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects}, abstract = {
Direct solid sampling by laser ablation into an inductively coupled plasma synchronous vertical dual view optical emission spectroscope (LA-SVDV-ICP-OES) was used for the elemental analysis of nutrient elements Ca, B, Mn, Mg, K, and Zn and essential (non-metallic) elements P and S in plant materials. The samples were mixed with paraffin as a binder, an approach that provides better cohesion of the particles in the pellets in addition to supplying carbon to serve as an internal standard (atomic line C I 193.027 nm) as a way to compensate for matrix effects, and/or variations in the ablation process. Precision was in the range of 1-8% relative standard deviation (RSD) with limit of detection in the range of 0.4-1 mg/kg-1 and 25-640 mg/kg-1 for metallic and non-metallic elements, respectively.
}, year = {2017}, journal = {Applied Spectroscopy}, volume = {71}, pages = {709 - 720}, month = {12/2016}, issn = {0003-7028}, doi = {10.1177/0003702816683686}, language = {eng}, }