@article{34199, author = {Fanglin Wu and Yizhi Yan and Rui Wang and Haopeng Cai and Wei Tong and Haolin Tang}, title = {Synthesis of LiNi1/3Mn1/3Co1/3O2@graphene for lithium-ion batteries via self-assembled polyelectrolyte layers}, abstract = {

LiNi1/3Co1/3Mn1/3O2 cathode coated with a thin layer of graphene (~8nm) is successfully synthesized by self-assembly and pyrolysis of polyelectrolyte layers on the surface of NMC particles. The graphene coated NMCs still possess a layered structure with good crystallinity and demonstrate a superior electrochemical performance (e.g., rate capability and cycling stability). The best graphene coated NMC cathode is prepared at a calcination temperature of 800°C, exhibiting a capacity retention of ~90% vs. 78% for pristine NMC @ cycle 100 and 1C rate. The improvement in cycling performance is further enlarged after 500 cycles (74% vs. 51%). This can be attributed to the dual functions of graphene coating in enhancing electronic conductivity and protecting NMC surface from the contact with electrolyte during the electrochemical reaction.

}, year = {2017}, journal = {Ceramics International}, volume = {43}, pages = {7668 - 7673}, month = {03/2017}, issn = {02728842}, doi = {10.1016/j.ceramint.2017.03.066}, language = {eng}, }