@article{34126,
  author = {Zhenyu Xing and Yitong Qi and Ziqi Tian and Jing Xu and Yifei Yuan and Clement Bommier and Jun Lu and Wei Tong and De-en Jiang and Xiulei Ji},
  title = {Identify the Removable Substructure in Carbon ActivationIdentify the Removable Substructure in Carbon Activation},
  abstract = {<p><span>Activated carbon plays a pivotal role in achieving critical functions, such as separation, catalysis, and energy storage. A remaining question of carbon activation is which substructures in amorphous carbon are preferentially removed during activation. Herein, we report the first structure–activation correlation elucidated on the basis of unprecedented comprehensive characterization on carbon activation. We discover that activation under CO</span><span>2</span><span>&nbsp;preferentially removes graphenic layers that are more defective. Therefore, the resulting activated carbon contains thinned turbostratic nanodomains that are of a higher local graphenic order. The mechanistic insights explain why more defective soft carbon is “burned” under CO</span><span>2</span><span>&nbsp;at a much faster rate than hard carbon. The mechanism leads to an activation-based design principle of mesoporous carbon. Guided by this principle, a bimodal micromesoporous carbon is prepared simply by CO</span><span>2</span><span>&nbsp;activation. Our findings may cause a paradigm shift for the rational design of nanoporous carbon.</span></p>},
  year = {2017},
  journal = {Chemistry of Materials},
  volume = {29},
  pages = {7288 - 7295},
  month = {07/2017},
  issn = {0897-4756},
  doi = {10.1021/acs.chemmater.7b0193710.1021/acs.chemmater.7b01937.s001},
  language = {eng},
}