@inproceedings{33727, keywords = {oxidation, thin films, glass, X ray diffraction, X ray photoelectron spectroscopy, Molybdenum, Desorption peak, Field emitter arrays, Partial oxidation, Thermal desorption spectroscopy, Ultraviolet photoelectron spectroscopy}, author = {B.R Chalamala and R.H Reuss and Y Wei and J.M Bernhard and E.D Sosa and D.E Golden and S Aggarwal and Ramamoorthy Ramesh}, title = {Oxidation of molybdenum thin films and its impact on molybdenum field emitter arrays}, abstract = {Oxidation of emitter surfaces can be a serious problem for Mo field emitter arrays. We studied the oxidation and related changes in the electronic properties of Mo thin films as a function of annealing temperature. Experiments were done on Mo thin films prepared on Si and sodalime glass substrates. These films were thermally oxidized and characterized using a variety of techniques including x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), and thermal desorption spectroscopy (TPD) methods. For films oxidized below 400°C, partial oxidation was observed, with MoO3(110) being the principal oxide phase. However, at a temperature of 500°C and above, oxidation of the film was complete. Electrical characteristics of the films undergo a rapid transition from semiconductive to highly insulating at temperatures between 475 to 500°C. Temperature programmed desorption spectra showed that the oxides are stable at elevated temperature with only a principal O2 desorption peak at approximately 786°C. © 2001 Materials Research Society.}, year = {2001}, journal = {Materials Research Society Symposium Proceedings}, volume = {685}, pages = {353-358}, issn = {02729172}, isbn = {1558996214; 9781558996212}, note = {cited By 0}, language = {eng}, }