@article{33715, keywords = {thin films, Electric fields, Polarization, Domain walls, Switching, Ferroelectric films, Ferroelectric thin films, Piezoresponse force microscopy, Bottom electrodes, Depolarizing fields, In-plane polarization, Initial orientation, Out-of-plane, Polydomain, Transient polarization, Depolarization}, author = {A Roelofs and N.A Pertsev and R Waser and F Schlaphof and L.M Eng and C Ganpule and V Nagarajan and Ramamoorthy Ramesh}, title = {Depolarizing-field-mediated 180° switching in ferroelectric thin films with 90° domains}, abstract = {Switching of the out-of-plane and in-plane polarizations in polydomain epitaxial PbZr0.2Ti0.8O3 thin films is studied using three-dimensional piezoresponse force microscopy (PFM). It is found that, under an electric field induced between the PFM tip and the bottom electrode, the 180° switching occurs in both c and a domains. After the removal of this field, the spontaneous reversal of the out-of-plane and in-plane polarizations back to the initial orientations takes place, evolving via heterogeneous development of antiparallel 180° domains. The switching of in-plane polarization inside a domains and the preferential formation of reversed 180° domains at 90° domain walls are explained by the effects of the depolarizing fields caused by transient polarization charges appearing on these domain walls. © 2002 American Institute of Physics.}, year = {2002}, journal = {Applied Physics Letters}, volume = {80}, number = {8}, pages = {1424-1426}, issn = {00036951}, doi = {10.1063/1.1448653}, note = {cited By 93}, language = {eng}, }