@article{33634, keywords = {Anisotropy, Oxide, Perovskite, Oxides, Substrates, Chemistry, Nanostructured materials, Nanostructures, Bismuth compounds, Article, Single crystals, Titanium, Calcium compounds, Single-crystal substrates, Calcium derivative, Nanomaterial, Nanopillars, Self-assembly, Perovskite spinel nanostructures, Surface energy anisotropy, Interfacial energy, Aluminum Oxide, Magnesium Oxide, Spinel}, author = {H Zheng and Q Zhan and F Zavaliche and M Sherburne and F Straub and M.P Cruz and L.-Q Chen and U Dahmen and Ramamoorthy Ramesh}, title = {Controlling self-assembled perovskite-spinel nanostructures}, abstract = {We report a discovery that self-assembled perovskite-spinel nanostructures can be controlled simply by selecting single-crystal substrates with different orientations. In a model BiFeO 3-CoFe 2O 4 system, a (001) substrate results in rectangular-shaped CoFe 2O 4 nanopillars in a BiFeO 3 matrix; in contrast, a (111) substrate leads to triangular-shaped BiFeO 3 nanopillars in a CoFe 2O 4 matrix, irrespective of the volume fraction of the two phases. This dramatic reversal is attributed to the surface energy anisotropy as an intrinsic property of a crystal. © 2006 American Chemical Society.}, year = {2006}, journal = {Nano Letters}, volume = {6}, number = {7}, pages = {1401-1407}, issn = {15306984}, doi = {10.1021/nl060401y}, note = {cited By 211}, language = {eng}, }