@article{33588, keywords = {Silicon compounds, Lanthanum compounds, Bismuth compounds, Permittivity, Epitaxial films, Hysteresis loops, Substitution reactions, Coercive voltage, Control domain structure, Rhombohedral distortion}, author = {Y.H Chu and Q Zhan and C.-H Yang and M.P Cruz and L.W Martin and T Zhao and P Yu and Ramamoorthy Ramesh and P.T Joseph and I.N Lin and W Tian and D.G Schlom}, title = {Low voltage performance of epitaxial BiFeO3 films on Si substrates through lanthanum substitution}, abstract = {We have probed the role of La substitution on the ferroelectric properties of epitaxial BiFe O3 films on SrTi O3 -templated Si. This provides a mechanism to engineer the rhombohedral distortion in the crystal and, thus, control domain structure and switching. With a 10% La substitution, the (Bi0.9 La0.1) Fe O3 film showed well-saturated ferroelectric hysteresis loops with a remanent polarization of 45 μC cm2, a converse piezoelectric coefficient d33 of 45 pmV, and a dielectric constant of 140. Over this range of La substitution, the coercive field systematically decreases such that a coercive voltage of 1 V can been obtained in a 100 nm thick film. These results show promise for the ultimate implementation of this lead-free multiferroic operating at voltages in the range of 2-3 V. © 2008 American Institute of Physics.}, year = {2008}, journal = {Applied Physics Letters}, volume = {92}, number = {10}, issn = {00036951}, doi = {10.1063/1.2897304}, note = {cited By 79}, language = {eng}, }