@article{33453, keywords = {Pulsed laser deposition, Copper, Films, Zinc oxide, Zno, Transparency, Heterojunctions, Semiconductor doping, Acceptor doping, Cu content, Hall effect measurement, Heterojunction diodes, High transparency, Hole conduction, Hole conductivity, P-type, S-phase, Transparent conducting materials, Transparent conductors, Semiconductor diodes, Zinc sulfide}, author = {A.M Diamond and L Corbellini and K.R Balasubramaniam and S Chen and S Wang and T.S Matthews and L.-W Wang and Ramamoorthy Ramesh and Joel W Ager}, title = {Copper-alloyed ZnS as a p-type transparent conducting material}, abstract = {Copper alloyed ZnS was investigated as a p-type, transparent conducting material composed of earth-abundant elements. Thin films of Cu-alloyed ZnS were synthesized using pulsed laser deposition with Cu contents in the range of x = 0.06-0.27 (Cu content x is reported as the fraction of cation present). Thermopower and Hall effect measurements show that the films are p-type. We find that transparency and conductivity are comparable to some of the best reported p-type materials with our best films exhibiting conductivities of 54 S cm -1 and optical transmission of 65% at 550. The hole conduction mechanism is discussed in terms of possible Cu acceptor doping of the ZnS and hole conductivity in a minority Cu2S phase. Transparent rectifying p-CuZnS/n-ZnO diodes were fabricated. Photo demonstrating the high transparency of a rectifying heterojunction diode made with p-type Cu-alloyed ZnS and n-type ZnO. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.}, year = {2012}, journal = {Physica Status Solidi (A) Applications and Materials Science}, volume = {209}, number = {11}, pages = {2101-2107}, issn = {18626300}, doi = {10.1002/pssa.201228181}, note = {cited By 58}, language = {eng}, }