@article{30093,
  author = {Xingcheng Xiao and Weidong Zhou and Youngnam Kim and Ill Ryu and Meng Gu and Chongmin Wang and Gao Liu and Zhongyi Liu and Huajian Gao},
  title = {Regulated Breathing Effect of Silicon Negative Electrode for Dramatically Enhanced Performance of Li-Ion Battery},
  abstract = {<p>Si is an attractive negative electrode material for lithium ion batteries due to its high specific capacity (≈3600 mAh g<sup>–1</sup>). However, the huge volume swelling and shrinking during cycling, which mimics a breathing effect at the material/electrode/cell level, leads to several coupled issues including fracture of Si particles, unstable solid electrolyte interphase, and low Coulombic efficiency. In this work, the regulation of the breathing effect is reported by using Si–C yolk–shell nanocomposite which has been well-developed by other researchers. The focus is on understanding how the nanoscaled materials design impacts the mechanical and electrochemical response at electrode level. For the first time, it is possible to observe one order of magnitude of reduction on breathing effect at the electrode level during cycling: the electrode thickness variation reduced down to 10%, comparing with 100% in the electrode with Si nanoparticles as active materials. The Si–C yolk–shell nanocomposite electrode exhibits excellent capacity retention and high cycle efficiency. In situ transmission electron microscopy and finite element simulations consistently reveals that the dramatically enhanced performance is associated with the regulated breathing of the Si in the new composite, therefore the suppression of the overall electrode expansion.</p>},
  year = {2015},
  journal = {Advanced Functional Materials},
  volume = {25},
  pages = {1426 - 1433},
  month = {01/2015},
  doi = {10.1002/adfm.v25.910.1002/adfm.201403629},
  language = {eng},
}