@article{30090, author = {Caihong Feng and Le Zhang and Menghuan Yang and Xiangyun Song and Hui Zhao and Zhe Jia and Kening Sun and Gao Liu}, title = {One-Pot Synthesis of Copper Sulfide Nanowires/Reduced Graphene Oxide Nanocomposites with Excellent Lithium-Storage Properties as Anode Materials for Lithium-Ion Batteries}, abstract = {
Copper sulfide nanowires/reduced graphene oxide (CuSNWs/rGO) nanocompsites are successfully synthesized via a facile one-pot and template-free solution method in a dimethyl sulfoxide (DMSO)–ethyl glycol (EG) mixed solvent. It is noteworthy that the precursor plays a crucial role in the formation of the nanocomposites structure. SEM, TEM, XRD, IR and Raman spectroscopy are used to investigate the morphological and structural evolution of CuSNWs/rGO nanocomposites. The as-fabricated CuSNWs/rGO nanocompsites show remarkably improved Li-storage performance, excellent cycling stability as well as high-rate capability compared with pristine CuS nanowires. It obtains a reversible capacity of 620 mAh g–1 at 0.5C (1C = 560 mA g–1) after 100 cycles and 320 mAh g–1 at a high current rate of 4C even after 430 cycles. The excellent lithium storage performance is ascribed to the synergistic effect between CuS nanowires and rGO nanosheets. The as-formed CuSNWs/rGO nanocomposites can effectively accommodate large volume changes, supply a 2D conducting network and trap the polysulfides generated during the conversion reaction of CuS.
}, year = {2015}, journal = {ACS Applied Materials & Interfaces}, volume = {7}, pages = {15726 - 15734}, month = {05/2017}, issn = {1944-8244}, doi = {10.1021/acsami.5b01285}, language = {eng}, }