@article{27549, keywords = {lithium battery, polymer electrolyte, nanostructure, self-assembly}, author = {Gao Liu and Melanie T Reinhout and Gregory L Baker}, title = {Nanoscale lithium ion conducting polyethylene oxide with self-attached insulating layers}, abstract = {

We report a new family of self-assembling nanostructured polymers for potential application as electrolytes in rechargeable lithium batteries. The ester groups of these amphiphilic methacrylate polymers are oligoethylene oxide segments terminated by a linear alkyl chain. The ethylene oxide segments are amorphous providing good lithium salt solubility and ionic conductivity, while the terminal alkyl segments crystallize and provide dimensional stability. The polymers self-assemble into nanometer-thick lamellar structures with alternating layers of conductive ethylene oxide and insulating alkyl layers.

}, year = {2004}, journal = {Solid State Ionics}, volume = {175}, number = {1-4}, pages = {721-724}, month = {11/2004}, language = {eng}, }