@article{25185,
  keywords = {Particle, Measurements, Measurement, USA, Pulse, Ablation, Laser, Laser ablation, Laser ablation, Analysis, Intensities, Intensity, Time, Ca, Composition, Fractionation, Glass, Glasses, Icp-ms, Icp-ms, Icp-ms, Inductively coupled plasma (icp), Inductively coupled plasma mass spectrometry, Inductively-coupled plasma, Mass, Mass spectrometry, Mass spectrometry, Plasma, Plasma mass spectrometry, Plasma-mass spectrometry, Sampling, Spectrometry, Ablated mass, Chemical analysis, Chemical analysis, Dependence, Emission spectroscopy, No, Ratio, Signal, Single, Crater, Volume, Correlation, Laser ablation sampling, Nist, Depth, Silicon, Glass samples, Elemental fractionation, Irradiance, Pb/u, Pulse laser, Pulse laser ablation, Segregation},
  author = {Haichen Liu and Xianglei Mao and Richard E Russo},
  title = {Representative sampling using single-pulse laser ablation with inductively coupled plasma mass spectrometry},
  abstract = {<p>Single pulse laser ablation sampling with inductively coupled plasma mass spectrometry (ICP-MS) was assessed for accurate chemical analysis. Elemental fractionation (<em>e.g.</em> Pb/U), the quantity of ablated mass (crater volume), ICP-MS intensity and the particle contribution (spike signal) during single pulse ablation of NIST 610 glass were investigated. Pb/U fractionation significantly changed between the first and second laser pulse and showed strong irradiance dependence. The Pb/U ratio obtained by the first pulse was usually higher than that of the second pulse, with the average value close to the representative level. Segregation during laser ablation is proposed to explain the composition change between the first and second pulse. Crater volume measurements showed that the second pulse produced significantly more ablated mass. A roll-off of the crater depth occurred at ~750&nbsp;GW&nbsp;cm<sup>-2</sup>. The absolute ICP-MS intensity from the second pulse showed no correlation with crater depth. Particle induced spikes on the transit signal showed irradiance and elemental species dependence.</p>},
  year = {2001},
  journal = { Journal of Analytical Atomic Spectrometry},
  volume = {16},
  number = {10},
  pages = {1115-1120},
  doi = {10.1039/B101421H },
  language = {eng},
}