@article{25172, author = {Zonghoon Lee and Ki-Joon Jeon and Albert Dato and Rolf Erni and Thomas J Richardson and Michael Frenklach and Velimir Radmilovic}, title = {Direct Imagining of Soft-hard Interfaces Enabled by Graphene}, abstract = {

Direct imaging of surface molecules and the interfaces between soft and hard materials on functionalized nanoparticles is a great challenge using modern microscopy techniques. We show that graphene, a single atomic layer of sp2-bonded carbon atoms, can be employed as an ultrathin support film that enables direct imaging of molecular layers and interfaces in both conventional and atomic-resolution transmission electron microscopy. An atomic-resolution imaging study of the capping layers and interfaces of citrate-stabilized gold nanoparticles is used to demonstrate this novel capability. Our findings reveal the unique potential of graphene as an ideal support film for atomic-resolution transmission electron microscopy of hard and soft nanomaterials.

}, year = {2009}, journal = {NanoLetters}, volume = {9}, pages = {3365-3369}, month = {09/2009}, doi = {10.1021/nl901664k}, language = {eng}, }